Praseodymium monosulfide

Praseodymium monosulfide
Names
IUPAC name
sulfanylidenepraseodymium(1+)
Other names
Praseodymium(II) sulfide
Identifiers
CAS Number
  • 12038-06-1
3D model (JSmol)
  • Interactive image
InChI
  • InChI=1S/Pr.S/q+2;-2
    Key: AESILDUJSAGKHP-UHFFFAOYSA-N
  • [S-2].[Pr+2]
Properties
Chemical formula
PrS
Molar mass 172.97 g·mol−1
Appearance Crystalline solid
Density 6.1 g/cm3
Melting point 2,230 °C (4,050 °F; 2,500 K)
Related compounds
Related compounds
Samarium monosulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Praseodymium monosulfide is a binary inorganic chemical compound of praseodymium metal and sulfur with the chemical formula PrS.[1][2]

Synthesis

Fusion of stoichiometric amounts of pure substances:

Pr + S → PrS

Physical properties

Praseodymium monosulfide forms crystals of the cubic system, space group Fm3m, cell parameters a = 0.5727 nm, Z = 4, structurally isomorphous with NaCl.[3][4][5]

The compound melts at a temperature of 2230 °C and has a homogeneity range of PrS0.75–1.

References

  1. ^ "WebElements Periodic Table » Praseodymium » praseodymium sulphide". webelements.com. Retrieved 25 July 2024.
  2. ^ "Praseodymium(II) Sulfide". American Elements. Retrieved 25 July 2024.
  3. ^ Okamoto, H. (1 October 1991). "Pr-S (Praseodymium-Sulfur)". Journal of Phase Equilibria. 12 (5): 618–619. doi:10.1007/BF02645088. ISSN 1054-9714. Retrieved 25 July 2024.
  4. ^ Predel, B. (1998). "Pr-S (Praseodymium-Sulfur)". Ni-Np – Pt-Zr. Landolt-Börnstein - Group IV Physical Chemistry. I: 1–2. doi:10.1007/10542753_2497. ISBN 3-540-61712-4. Retrieved 25 July 2024.
  5. ^ Swanson, Howard Eugene (1962). Standard X-ray Diffraction Powder Patterns: Data for 46 substances. National Bureau of Standards. p. 67. Retrieved 25 July 2024.
  • v
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Praseodymium compounds
Pr(II)
  • PrI2
  • PrSe
  • PrS
  • PrP5
Pr(III)
  • Pr(NO3)3
  • Pr2(SO4)3
  • Pr2(SeO4)3
  • PrF3
  • PrCl3
  • PrBr3
  • PrI3
  • PrN
  • PrP
  • PrAs
  • PrSb
  • PrBi
  • PrOI
  • PrB4
  • PrB6
  • Pr(CH3COO)3
  • Pr(OH)3
  • Pr2O3
  • Pr2S3
  • Pr(ClO4)3
  • Pr(BrO3)3
  • Pr(IO3)3
  • Pr2(MoO4)3
  • PrPO4
  • Pr(C5H7O2)3
  • PrAsO4
  • PrScO3
  • C6O12Pr2
Organopraseodymium(III) compounds
  • Pr2(CO3)3
  • Pr2(C2O4)3
  • Pr(III,IV)
    • Pr6O11
    Pr(IV)
    • PrF4
    • PrO2
    Pr(V)
    • PrNO
    • v
    • t
    • e
    Sulfides (S2−)
    H2S He
    Li2S BeS B2S3
    +BO3
    CS2
    COS
    (NH4)SH O F Ne
    Na2S MgS Al2S3 SiS
    SiS2
    -Si
    PxSy
    -P
    -S2−
    2
    Cl Ar
    K2S CaS ScS
    Sc2S3
    TiS
    TiS2
    Ti2S3
    TiS3
    VS
    VS2
    V2S3
    CrS
    Cr2S3
    MnS
    MnS2
    FeS
    Fe3S4
    CoxSy NixSy Cu2S
    CuS
    ZnS GaS
    Ga2S3
    GeS
    GeS2
    -Ge
    As2S3
    As4S3
    -As
    SeS2
    +Se
    Br Kr
    Rb2S SrS Y2S3 ZrS2 NbS2 MoS2
    MoS3
    TcS2
    Tc2S7
    Ru Rh2S3 PdS Ag2S CdS In2S3 SnS
    SnS2
    -Sn
    Sb2S3
    Sb2S5
    -Sb
    TeS2 I Xe
    Cs2S BaS * LuS
    Lu2S3
    HfS2 TaS2 WS2
    WS3
    ReS2
    Re2S7
    OsS
    4
    Ir2S3
    IrS2
    PtS
    PtS2
    Au2S
    Au2S3
    HgS Tl2S PbS
    PbS2
    Bi2S3 PoS At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * LaS
    La2S3
    CeS
    Ce2S3
    PrS
    Pr2S3
    NdS
    Nd2S3
    PmS
    Pm2S3
    SmS
    Sm2S3
    EuS
    Eu2S3
    GdS
    Gd2S3
    TbS
    Tb2S3
    DyS
    Dy2S3
    HoS
    Ho2S3
    ErS
    Er2S3
    TmS
    Tm2S3
    YbS
    Yb2S3
    ** Ac2S3 ThS2 Pa US
    US2
    Np Pu Am Cm Bk Cf Es Fm Md No