Lead(II) phosphate

Lead(II) phosphate
Names
Systematic IUPAC name
Lead(II) phosphate
Identifiers
CAS Number
  • 7446-27-7 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 22442 checkY
ECHA InfoCard 100.028.368 Edit this at Wikidata
EC Number
  • 231-205-5
PubChem CID
  • 24009
RTECS number
  • OG3675000
UNII
  • 62I1T06190 checkY
UN number 3288 2291
CompTox Dashboard (EPA)
  • DTXSID5064706 Edit this at Wikidata
InChI
  • InChI=1S/2H3O4P.3Pb/c2*1-5(2,3)4;;;/h2*(H3,1,2,3,4);;;/q;;3*+2/p-6 ☒N
    Key: HUTDDBSSHVOYJR-UHFFFAOYSA-H ☒N
  • [O-]P(=O)([O-])[O-].[O-]P(=O)([O-])[O-].[Pb+2].[Pb+2].[Pb+2]
Properties
Chemical formula
Pb3(PO4)2
Molar mass 811.54272 g/mol
Appearance white powder
Density 6.9 g/cm3
Melting point 1,014 °C (1,857 °F; 1,287 K)
Solubility in water
0.000014 g/100 mL
Solubility insoluble in alcohol
soluble in nitric acid
Magnetic susceptibility (χ)
−182.0·10−6 cm3/mol
Refractive index (nD)
2.048
Hazards
GHS labelling:[1]
Pictograms
GHS08: Health hazardGHS09: Environmental hazard
Warning
Hazard statements
H360Df, H373, H410
Precautionary statements
P203, P260, P273, P280, P318, P319, P391, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

Lead(II) phosphate is an ionic compound with chemical formula Pb3(PO4)2. Lead(II) phosphate is a long-lived electronically neutral reagent chemical.[2] Despite limited tests on humans, it has been identified as a carcinogen based on tests on animals conducted by the EPA.[3] Lead(II) phosphate appears as hexagonal, colorless crystals or as a white powder. Lead(II) phosphate is insoluble in water and alcohol but soluble in nitric acid (HNO3) and fused alkali metal hydroxides. When lead(II) phosphate is heated for decomposition it emits very toxic fumes containing Lead (Pb) and POx.[4]

Preparation

It is prepared by reacting lead(II) hydroxide with orthophosphoric acid.

3Pb(OH)2 + 2H3PO4 → Pb3(PO4)2 + 6H2O

References

  1. ^ "Lead phosphate". pubchem.ncbi.nlm.nih.gov. Retrieved 27 April 2023.
  2. ^ "Lead(II) phosphate". The Chemical Thesaurus. Retrieved 11 October 2010.
  3. ^ Wright, John, (2003). Environmental Chemistry pg 211. New York (NY): Routledge.
  4. ^ Lewis, Richard J., Lewis, Richard J. Sr., (2008). Hazardous chemicals desk reference (sixth ed.) pg 831. Hoboken (NJ): John Wiley & Sons, Inc.
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Lead compounds
Pb(II)
  • Pb(BiO3)2
  • PbBr2
  • Pb(C5H5)2
  • Pb(C2H3O2)2
  • PbC2O4
  • PbC32H16N8
  • PbCl2
  • Pb(ClO4)2
  • PbCO3
  • PbCrO4
  • PbF2
  • PbHAsO4
  • PbI2
  • Pb(C
    11
    H
    23
    COO)
    2
  • Pb(NO3)2
  • Pb(N3)2
  • PbO
  • Pb(OH)2
  • PbPo
  • PbP7
  • Pb3(PO4)2
  • PbS
  • Pb(SCN)2
  • PbSe
  • PbSO4
  • PbSeO4
  • PbTe
  • PbTiO3
  • PbGeO3
  • C
    36
    H
    70
    PbO
    4
  • plumbite
  • PbC2 (hypothetical)
Pb(II,IV)
  • Pb3O4
Pb(IV)
  • Pb(C2H3O2)4
  • PbCl4
  • PbF4
  • PbH4
  • PbO2
  • PbS2
  • plumbate
  • Pb(OH)4 (hypothetical)
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H3PO4
[HPO4]2−
[H2PO4]
He
Li3PO4 Be BPO4
+BO3
C (NH4)3PO4
(NH4)2HPO4
NH4H2PO4
-N
O +F Ne
Na3PO4
Na2HPO4
NaH2PO4
Mg3(PO4)2 AlPO4 Si P +SO4
-S
Cl Ar
K3PO4
K2HPO4
KH2PO4
Ca3(PO4)2 ScPO4 Ti VPO4 CrPO4 Mn3(PO4)2
MnPO4
Fe3(PO4)2
FePO4
Co3(PO4)2 Ni3(PO4)2 Cu3(PO4)2 Zn3(PO4)2 GaPO4 Ge As -Se Br Kr
Rb3PO4 Sr3(PO4)2 YPO4 Zr3(PO4)4 Nb Mo Tc Ru Rh Pd Ag3PO4 Cd3(PO4)2 InPO4 Sn SbPO4
-SbO4
Te I Xe
Cs3PO4 Ba3(PO4)2 * LuPO4 Hf Ta W Re Os Ir Pt AuPO4 Hg Tl3PO4 Pb3(PO4)2 BiPO4 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaPO4 CePO4 PrPO4 NdPO4 PmPO4 SmPO4 EuPO4 GdPO4 TbPO4 DyPO4 HoPO4 ErPO4 TmPO4 YbPO4
** AcPO4 Th3(PO4)4 Pa U(PO4)2 Np PuPO4 AmPO4 CmPO4 Bk Cf Es Fm Md No


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